Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR

Vladimir V. Matveev, Mikhail Zubkov, Erkki Lähderanta, Petri Ingman, Oleg N. Kalugin, Ashok K. Adya

Research output: Contribution to journalArticle

14 Downloads (Pure)

Abstract

1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.
Original languageEnglish
Pages (from-to) 746-752
Number of pages7
JournalPhysics and Chemistry of Liquids
Volume49
Issue number6
DOIs
Publication statusPublished - Sep 2011

Fingerprint

Solvation
solvation
Cations
Positive ions
Nuclear magnetic resonance
cations
nuclear magnetic resonance
Methanol
methyl alcohol
Chemical analysis
time signals
Anions
Negative ions
anions
Temperature
temperature

Cite this

Matveev, V. V., Zubkov, M., Lähderanta, E., Ingman, P., Kalugin, O. N., & Adya, A. K. (2011). Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. Physics and Chemistry of Liquids, 49(6), 746-752. https://doi.org/10.1080/00319104.2010.513334
Matveev, Vladimir V. ; Zubkov, Mikhail ; Lähderanta, Erkki ; Ingman, Petri ; Kalugin, Oleg N. ; Adya, Ashok K. / Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. In: Physics and Chemistry of Liquids. 2011 ; Vol. 49, No. 6. pp. 746-752.
@article{f0976ff5d2e1420986c36a319d577133,
title = "Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR",
abstract = "1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.",
author = "Matveev, {Vladimir V.} and Mikhail Zubkov and Erkki L{\"a}hderanta and Petri Ingman and Kalugin, {Oleg N.} and Adya, {Ashok K.}",
year = "2011",
month = "9",
doi = "10.1080/00319104.2010.513334",
language = "English",
volume = "49",
pages = "746--752",
journal = "Physics and Chemistry of Liquids",
issn = "0031-9104",
publisher = "Taylor and Francis Ltd.",
number = "6",

}

Matveev, VV, Zubkov, M, Lähderanta, E, Ingman, P, Kalugin, ON & Adya, AK 2011, 'Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR', Physics and Chemistry of Liquids, vol. 49, no. 6, pp. 746-752. https://doi.org/10.1080/00319104.2010.513334

Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. / Matveev, Vladimir V.; Zubkov, Mikhail; Lähderanta, Erkki; Ingman, Petri; Kalugin, Oleg N.; Adya, Ashok K.

In: Physics and Chemistry of Liquids, Vol. 49, No. 6, 09.2011, p. 746-752.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR

AU - Matveev, Vladimir V.

AU - Zubkov, Mikhail

AU - Lähderanta, Erkki

AU - Ingman, Petri

AU - Kalugin, Oleg N.

AU - Adya, Ashok K.

PY - 2011/9

Y1 - 2011/9

N2 - 1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.

AB - 1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.

U2 - 10.1080/00319104.2010.513334

DO - 10.1080/00319104.2010.513334

M3 - Article

VL - 49

SP - 746

EP - 752

JO - Physics and Chemistry of Liquids

JF - Physics and Chemistry of Liquids

SN - 0031-9104

IS - 6

ER -