Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR

Vladimir V. Matveev, Mikhail Zubkov, Erkki Lähderanta, Petri Ingman, Oleg N. Kalugin, Ashok K. Adya

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Abstract

1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.
Original languageEnglish
Pages (from-to) 746-752
Number of pages7
JournalPhysics and Chemistry of Liquids
Volume49
Issue number6
DOIs
Publication statusPublished - Sep 2011

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Solvation
solvation
Cations
Positive ions
Nuclear magnetic resonance
cations
nuclear magnetic resonance
Methanol
methyl alcohol
Chemical analysis
time signals
Anions
Negative ions
anions
Temperature
temperature

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Matveev, V. V., Zubkov, M., Lähderanta, E., Ingman, P., Kalugin, O. N., & Adya, A. K. (2011). Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. Physics and Chemistry of Liquids, 49(6), 746-752. https://doi.org/10.1080/00319104.2010.513334
Matveev, Vladimir V. ; Zubkov, Mikhail ; Lähderanta, Erkki ; Ingman, Petri ; Kalugin, Oleg N. ; Adya, Ashok K. / Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. In: Physics and Chemistry of Liquids. 2011 ; Vol. 49, No. 6. pp. 746-752.
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abstract = "1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.",
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Matveev, VV, Zubkov, M, Lähderanta, E, Ingman, P, Kalugin, ON & Adya, AK 2011, 'Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR', Physics and Chemistry of Liquids, vol. 49, no. 6, pp. 746-752. https://doi.org/10.1080/00319104.2010.513334

Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. / Matveev, Vladimir V.; Zubkov, Mikhail; Lähderanta, Erkki; Ingman, Petri; Kalugin, Oleg N.; Adya, Ashok K.

In: Physics and Chemistry of Liquids, Vol. 49, No. 6, 09.2011, p. 746-752.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR

AU - Matveev, Vladimir V.

AU - Zubkov, Mikhail

AU - Lähderanta, Erkki

AU - Ingman, Petri

AU - Kalugin, Oleg N.

AU - Adya, Ashok K.

PY - 2011/9

Y1 - 2011/9

N2 - 1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.

AB - 1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.

U2 - 10.1080/00319104.2010.513334

DO - 10.1080/00319104.2010.513334

M3 - Article

VL - 49

SP - 746

EP - 752

JO - Physics and Chemistry of Liquids

JF - Physics and Chemistry of Liquids

SN - 0031-9104

IS - 6

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Matveev VV, Zubkov M, Lähderanta E, Ingman P, Kalugin ON, Adya AK. Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR. Physics and Chemistry of Liquids. 2011 Sep;49(6): 746-752. https://doi.org/10.1080/00319104.2010.513334

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