Composition of Ni2+ cation solvation shell in NiCl2–methanol solution by multinuclear NMR

Vladimir V. Matveev, Mikhail Zubkov, Erkki Lähderanta, Petri Ingman, Oleg N. Kalugin, Ashok K. Adya

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Abstract

1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.
Original languageEnglish
Pages (from-to) 746-752
Number of pages7
JournalPhysics and Chemistry of Liquids
Volume49
Issue number6
DOIs
Publication statusPublished - Sep 2011

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