Abstract
1H-, 2H- and 13C-NMR spectra have been used to test the Ni2+ solvation shell composition in the 1.1 molal methanol solution of NiCl2. It has been confirmed that Cl− anion takes part in the nearest environment of Ni2+ cation at all the temperatures investigated. Using 2H-NMR allowed us to detect for the first time OD-signal of methanol in the primary solvation shell of Ni2+ cation. Both 2H- and 13C-NMR spectra show that the composition of the cation solvation shell becomes more complicated at temperatures lower than 220 K.
Original language | English |
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Pages (from-to) | 746-752 |
Number of pages | 7 |
Journal | Physics and Chemistry of Liquids |
Volume | 49 |
Issue number | 6 |
DOIs | |
Publication status | Published - Sep 2011 |