Electronic properties of amorphous carbon nitride a-C1-xNx: H films investigated using vibrational and ESR characterisations

M. Lacerda; M. Lejeune; B. J. Jones; R. C. Barklie; R. Bouzerar; K. Zellama; N. M.J. Conway; C. Godet

doi:10.1016/S0022-3093(01)00990-5

Electronic properties of amorphous carbon nitride a-C_1-xN_x: H films investigated using vibrational and ESR characterisations

M. Lacerda^*, M. Lejeune, B. J. Jones, R. C. Barklie, R. Bouzerar, K. Zellama, N. M.J. Conway, C. Godet

^*Corresponding author for this work

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

A combination of electron spin resonance and Raman spectroscopy measurements is applied to fully characterise a-C_1-xN_x:H films (x ≤ 20 at.%), grown by plasma decomposition of C₂H₂-N₂ mixtures. The observed decrease in the spin density (8.5 × 10₁₉-1.6 × 10₁₉ cm_-3) when the N content increases is consistent with the decrease in the disorder of the sp² nanostructure evidenced by resonant Raman spectroscopy (at 488 and 514.5 nm excitations), which shows an increase in the I_D/I_G ratio and a narrowing of the D-peak.

Original language	English
Pages (from-to)	907-911
Number of pages	5
Journal	Journal of Non-Crystalline Solids
Volume	299-302
Issue number	PART 2
DOIs	https://doi.org/10.1016/S0022-3093(01)00990-5
Publication status	Published - Apr 2002
Externally published	Yes

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Lacerda, M., Lejeune, M., Jones, B. J., Barklie, R. C., Bouzerar, R., Zellama, K., Conway, N. M. J., & Godet, C. (2002). Electronic properties of amorphous carbon nitride a-C_1-xN_x: H films investigated using vibrational and ESR characterisations. Journal of Non-Crystalline Solids, 299-302(PART 2), 907-911. https://doi.org/10.1016/S0022-3093(01)00990-5

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title = "Electronic properties of amorphous carbon nitride a-C1-xNx: H films investigated using vibrational and ESR characterisations",

abstract = "A combination of electron spin resonance and Raman spectroscopy measurements is applied to fully characterise a-C1-xNx:H films (x ≤ 20 at.%), grown by plasma decomposition of C2H2-N2 mixtures. The observed decrease in the spin density (8.5 × 1019-1.6 × 1019 cm-3) when the N content increases is consistent with the decrease in the disorder of the sp2 nanostructure evidenced by resonant Raman spectroscopy (at 488 and 514.5 nm excitations), which shows an increase in the ID/IG ratio and a narrowing of the D-peak.",

author = "M. Lacerda and M. Lejeune and Jones, {B. J.} and Barklie, {R. C.} and R. Bouzerar and K. Zellama and Conway, {N. M.J.} and C. Godet",

year = "2002",

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doi = "10.1016/S0022-3093(01)00990-5",

language = "English",

volume = "299-302",

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journal = "Journal of Non-Crystalline Solids",

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Electronic properties of amorphous carbon nitride a-C_1-xN_x : H films investigated using vibrational and ESR characterisations. / Lacerda, M.; Lejeune, M.; Jones, B. J.; Barklie, R. C.; Bouzerar, R.; Zellama, K.; Conway, N. M.J.; Godet, C.

In: Journal of Non-Crystalline Solids, Vol. 299-302, No. PART 2, 04.2002, p. 907-911.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Electronic properties of amorphous carbon nitride a-C1-xNx

T2 - H films investigated using vibrational and ESR characterisations

AU - Lacerda, M.

AU - Lejeune, M.

AU - Jones, B. J.

AU - Barklie, R. C.

AU - Bouzerar, R.

AU - Zellama, K.

AU - Conway, N. M.J.

AU - Godet, C.

PY - 2002/4

Y1 - 2002/4

N2 - A combination of electron spin resonance and Raman spectroscopy measurements is applied to fully characterise a-C1-xNx:H films (x ≤ 20 at.%), grown by plasma decomposition of C2H2-N2 mixtures. The observed decrease in the spin density (8.5 × 1019-1.6 × 1019 cm-3) when the N content increases is consistent with the decrease in the disorder of the sp2 nanostructure evidenced by resonant Raman spectroscopy (at 488 and 514.5 nm excitations), which shows an increase in the ID/IG ratio and a narrowing of the D-peak.

AB - A combination of electron spin resonance and Raman spectroscopy measurements is applied to fully characterise a-C1-xNx:H films (x ≤ 20 at.%), grown by plasma decomposition of C2H2-N2 mixtures. The observed decrease in the spin density (8.5 × 1019-1.6 × 1019 cm-3) when the N content increases is consistent with the decrease in the disorder of the sp2 nanostructure evidenced by resonant Raman spectroscopy (at 488 and 514.5 nm excitations), which shows an increase in the ID/IG ratio and a narrowing of the D-peak.

U2 - 10.1016/S0022-3093(01)00990-5

DO - 10.1016/S0022-3093(01)00990-5

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VL - 299-302

SP - 907

EP - 911

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

SN - 0022-3093

IS - PART 2

ER -