Layered LixMn1-yNiyO2 intercalation electrodes

Tracey E. Quine, Morven J. Duncan, A. Robert Armstrong, Alastair D. Robertson, Peter G. Bruce

Research output: Contribution to journalArticle

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Abstract

Synthesis of the layered lithium intercalation compound LixMn1 − yNiyO2, with the O3 (α-NaFeO2) structure is reported and it is shown to exhibit amongst the highest capacity to cycle lithium (charge) on intercalation/deintercalation (220 mA h g−1 between potential limits of 2.4 to 4.8 V) of any such material and at a relatively high charge/discharge rate; the ion exchange conditions used in the synthesis have an important influence on the defect chemistry of the host structure and this in turn influences the performance of the compound as an electrode in rechargeable lithium batteries.

Original languageEnglish
Pages (from-to)2838-2841
Number of pages4
JournalJournal of Materials Chemistry
Volume10
Issue number12
DOIs
Publication statusPublished - 1 Dec 2000
Externally publishedYes

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Intercalation
Lithium Compounds
Lithium
Intercalation compounds
Electrodes
Lithium batteries
Ion exchange
Defects

Cite this

Quine, T. E., Duncan, M. J., Armstrong, A. R., Robertson, A. D., & Bruce, P. G. (2000). Layered LixMn1-yNiyO2 intercalation electrodes. Journal of Materials Chemistry, 10(12), 2838-2841. https://doi.org/10.1039/b007429m
Quine, Tracey E. ; Duncan, Morven J. ; Armstrong, A. Robert ; Robertson, Alastair D. ; Bruce, Peter G. / Layered LixMn1-yNiyO2 intercalation electrodes. In: Journal of Materials Chemistry. 2000 ; Vol. 10, No. 12. pp. 2838-2841.
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Quine, TE, Duncan, MJ, Armstrong, AR, Robertson, AD & Bruce, PG 2000, 'Layered LixMn1-yNiyO2 intercalation electrodes', Journal of Materials Chemistry, vol. 10, no. 12, pp. 2838-2841. https://doi.org/10.1039/b007429m

Layered LixMn1-yNiyO2 intercalation electrodes. / Quine, Tracey E.; Duncan, Morven J.; Armstrong, A. Robert; Robertson, Alastair D.; Bruce, Peter G.

In: Journal of Materials Chemistry, Vol. 10, No. 12, 01.12.2000, p. 2838-2841.

Research output: Contribution to journalArticle

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T1 - Layered LixMn1-yNiyO2 intercalation electrodes

AU - Quine, Tracey E.

AU - Duncan, Morven J.

AU - Armstrong, A. Robert

AU - Robertson, Alastair D.

AU - Bruce, Peter G.

PY - 2000/12/1

Y1 - 2000/12/1

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AB - Synthesis of the layered lithium intercalation compound LixMn1 − yNiyO2, with the O3 (α-NaFeO2) structure is reported and it is shown to exhibit amongst the highest capacity to cycle lithium (charge) on intercalation/deintercalation (220 mA h g−1 between potential limits of 2.4 to 4.8 V) of any such material and at a relatively high charge/discharge rate; the ion exchange conditions used in the synthesis have an important influence on the defect chemistry of the host structure and this in turn influences the performance of the compound as an electrode in rechargeable lithium batteries.

U2 - 10.1039/b007429m

DO - 10.1039/b007429m

M3 - Article

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JO - Journal of Materials Chemistry

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