Layered lithium manganese oxide-based cathode materials for Li-ion battery applications

A. D. Robertson, A. R. Armstrong, R. Gitzendanner, P. G. Bruce

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Recently, the layered (α-NaFeO2 type) lithium manganese oxide LiMnO2 was prepared by ion-exchange from the corresponding sodium phase (1). Subsequent neutron diffraction and high resolution transmission electron microscopy studies have shown that there is a coexistence of layered and spinel phases after galvanostatic cycling (2). The amount of spinel increases with repeated cycling. In order to try and stabilise the layered structure, substitution of some of the Mn by Co has been investigated by a variety of techniques including slow sweep cyclic voltammetry, galvanostatic cycling and powder X-ray and neutron diffraction structural studies on as-prepared and cycled samples (3).
Original languageEnglish
Title of host publicationProceedings of the symposium on lithium batteries
EditorsSubbarao Surampudi, Richard Marsh
Place of PublicationPennington, NJ
PublisherThe Electrochemical Society
Pages306-307
Number of pages2
Volume98-16
ISBN (Print)1566772109, 9781566772105
Publication statusPublished - 1999
Externally publishedYes
Event194th Electrochemical Society Fall Meeting - Boston, United States
Duration: 1 Nov 19986 Nov 1998
Conference number: 194

Other

Other194th Electrochemical Society Fall Meeting
CountryUnited States
CityBoston
Period1/11/986/11/98

Fingerprint

Neutron diffraction
Cathodes
High resolution transmission electron microscopy
Powders
Cyclic voltammetry
Ion exchange
Substitution reactions
Sodium
X ray diffraction
spinell
Lithium-ion batteries
lithium manganese oxide

Cite this

Robertson, A. D., Armstrong, A. R., Gitzendanner, R., & Bruce, P. G. (1999). Layered lithium manganese oxide-based cathode materials for Li-ion battery applications. In S. Surampudi, & R. Marsh (Eds.), Proceedings of the symposium on lithium batteries (Vol. 98-16, pp. 306-307). Pennington, NJ: The Electrochemical Society.
Robertson, A. D. ; Armstrong, A. R. ; Gitzendanner, R. ; Bruce, P. G. / Layered lithium manganese oxide-based cathode materials for Li-ion battery applications. Proceedings of the symposium on lithium batteries. editor / Subbarao Surampudi ; Richard Marsh. Vol. 98-16 Pennington, NJ : The Electrochemical Society, 1999. pp. 306-307
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abstract = "Recently, the layered (α-NaFeO2 type) lithium manganese oxide LiMnO2 was prepared by ion-exchange from the corresponding sodium phase (1). Subsequent neutron diffraction and high resolution transmission electron microscopy studies have shown that there is a coexistence of layered and spinel phases after galvanostatic cycling (2). The amount of spinel increases with repeated cycling. In order to try and stabilise the layered structure, substitution of some of the Mn by Co has been investigated by a variety of techniques including slow sweep cyclic voltammetry, galvanostatic cycling and powder X-ray and neutron diffraction structural studies on as-prepared and cycled samples (3).",
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Robertson, AD, Armstrong, AR, Gitzendanner, R & Bruce, PG 1999, Layered lithium manganese oxide-based cathode materials for Li-ion battery applications. in S Surampudi & R Marsh (eds), Proceedings of the symposium on lithium batteries. vol. 98-16, The Electrochemical Society, Pennington, NJ, pp. 306-307, 194th Electrochemical Society Fall Meeting, Boston, United States, 1/11/98.

Layered lithium manganese oxide-based cathode materials for Li-ion battery applications. / Robertson, A. D.; Armstrong, A. R.; Gitzendanner, R.; Bruce, P. G.

Proceedings of the symposium on lithium batteries. ed. / Subbarao Surampudi; Richard Marsh. Vol. 98-16 Pennington, NJ : The Electrochemical Society, 1999. p. 306-307.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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T1 - Layered lithium manganese oxide-based cathode materials for Li-ion battery applications

AU - Robertson, A. D.

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N2 - Recently, the layered (α-NaFeO2 type) lithium manganese oxide LiMnO2 was prepared by ion-exchange from the corresponding sodium phase (1). Subsequent neutron diffraction and high resolution transmission electron microscopy studies have shown that there is a coexistence of layered and spinel phases after galvanostatic cycling (2). The amount of spinel increases with repeated cycling. In order to try and stabilise the layered structure, substitution of some of the Mn by Co has been investigated by a variety of techniques including slow sweep cyclic voltammetry, galvanostatic cycling and powder X-ray and neutron diffraction structural studies on as-prepared and cycled samples (3).

AB - Recently, the layered (α-NaFeO2 type) lithium manganese oxide LiMnO2 was prepared by ion-exchange from the corresponding sodium phase (1). Subsequent neutron diffraction and high resolution transmission electron microscopy studies have shown that there is a coexistence of layered and spinel phases after galvanostatic cycling (2). The amount of spinel increases with repeated cycling. In order to try and stabilise the layered structure, substitution of some of the Mn by Co has been investigated by a variety of techniques including slow sweep cyclic voltammetry, galvanostatic cycling and powder X-ray and neutron diffraction structural studies on as-prepared and cycled samples (3).

M3 - Conference contribution

SN - 1566772109

SN - 9781566772105

VL - 98-16

SP - 306

EP - 307

BT - Proceedings of the symposium on lithium batteries

A2 - Surampudi, Subbarao

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Robertson AD, Armstrong AR, Gitzendanner R, Bruce PG. Layered lithium manganese oxide-based cathode materials for Li-ion battery applications. In Surampudi S, Marsh R, editors, Proceedings of the symposium on lithium batteries. Vol. 98-16. Pennington, NJ: The Electrochemical Society. 1999. p. 306-307