Phase diagrams and crystal chemistry in the Li+ ion conducting perovskites, Li0.5−3xRE0.5+x TiO3: RE = La, Nd

A. D. Robertson, S. Garcia Martin, A. Coats, A. R. West

Research output: Contribution to journalArticle

119 Citations (Scopus)

Abstract

The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li0.5−3xRE0.5+x TiO3: RE = La, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in the Nd system) are presented, together with data on the composition and thermal history dependence of the lattice parameters. The phase composition and microstructure of selected ceramic samples were analysed by electron microprobe techniques.

Original languageEnglish
Pages (from-to)1405-1412
Number of pages8
JournalJournal of Materials Chemistry
Volume5
Issue number9
DOIs
Publication statusPublished - 1995
Externally publishedYes

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Crystal chemistry
Polymorphism
Phase diagrams
Ions
Chemical analysis
Phase composition
Stoichiometry
Perovskite
Lattice constants
Solid solutions
Microstructure
Electrons
Temperature
Hot Temperature
perovskite

Cite this

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title = "Phase diagrams and crystal chemistry in the Li+ ion conducting perovskites, Li0.5−3xRE0.5+x TiO3: RE = La, Nd",
abstract = "The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li0.5−3xRE0.5+x TiO3: RE = La, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in the Nd system) are presented, together with data on the composition and thermal history dependence of the lattice parameters. The phase composition and microstructure of selected ceramic samples were analysed by electron microprobe techniques.",
author = "Robertson, {A. D.} and Martin, {S. Garcia} and A. Coats and West, {A. R.}",
year = "1995",
doi = "10.1039/JM9950501405",
language = "English",
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Phase diagrams and crystal chemistry in the Li+ ion conducting perovskites, Li0.5−3xRE0.5+x TiO3 : RE = La, Nd. / Robertson, A. D.; Martin, S. Garcia; Coats, A.; West, A. R.

In: Journal of Materials Chemistry, Vol. 5, No. 9, 1995, p. 1405-1412.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Phase diagrams and crystal chemistry in the Li+ ion conducting perovskites, Li0.5−3xRE0.5+x TiO3

T2 - RE = La, Nd

AU - Robertson, A. D.

AU - Martin, S. Garcia

AU - Coats, A.

AU - West, A. R.

PY - 1995

Y1 - 1995

N2 - The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li0.5−3xRE0.5+x TiO3: RE = La, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in the Nd system) are presented, together with data on the composition and thermal history dependence of the lattice parameters. The phase composition and microstructure of selected ceramic samples were analysed by electron microprobe techniques.

AB - The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li0.5−3xRE0.5+x TiO3: RE = La, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in the Nd system) are presented, together with data on the composition and thermal history dependence of the lattice parameters. The phase composition and microstructure of selected ceramic samples were analysed by electron microprobe techniques.

U2 - 10.1039/JM9950501405

DO - 10.1039/JM9950501405

M3 - Article

AN - SCOPUS:37049075214

VL - 5

SP - 1405

EP - 1412

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

SN - 0959-9428

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