Pore-scale visualization of colloid transport and retention in partly saturated porous media

John T. Crist, John F. McCarthy, Yuniati Zevi, Philippe C. Baveye, James A. Throop, Tammo S. Steenhuis

    Research output: Contribution to journalArticlepeer-review

    107 Citations (Scopus)

    Abstract

    In unsaturated porous media, sorption of colloids at the air–water (AW) interface is accepted as a mechanism for controlling colloid retention and mobilization. However, limited actual pore-scale observations of colloid attachment to the AW interface have been made. To further investigate these processes, a real-time pore-scale visualization method was developed. The method builds on the light transmission technique for fingered flow studies in packed-sand infiltration chambers and combines it with high-resolution, electro-optical hardware and public domain imaging software. Infiltration and drainage of suspensions of hydrophilic negatively charged carboxylated latex microspheres provides compelling visual evidence that colloid retention in sandy porous media occurs via trapping in the thin film of water where the AW interface and the solid interface meet, the air–water–solid (AWS) interface. With this modified theory of trapped colloids at the AWS interface, we are able to explain the apparent discrepancy between previous experimental evidence of hydrophilic colloids seemingly partitioning to the AW interface and more recent findings that suggest this type of colloid does not adsorb at the AW interface.
    Original languageEnglish
    Pages (from-to)444-450
    Number of pages7
    JournalVadose Zone Journal
    Volume3
    DOIs
    Publication statusPublished - May 2004

    Keywords

    • Air-water interface
    • Pore volume

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