Synthesis of the new high pressure vernier phase Sr0.74CuO 2

P. V.P.S.S. Sastry*, Alastair D. Robertson, Eric E. Lachowski, Alison Coats, Anthony R. West

*Corresponding author for this work

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Abstract

The strontium oxide-copper oxide binary phase diagram has been reinvestigated under oxygen pressures of up to 600 bar, in the temperature range 600-850 °C. A new, high-pressure phase, Sr0.74CuO2, has been isolated and characterised. The oxygen stoichiometry, confirmed by thermogravimetry, gives an average formal copper valence of ca. 2.5. X-Ray and electron diffraction analyses suggest that Sr0.74CuO2 has a Vernier structure incommensurate in b. The subcells are body-centred orthorhombic: aI=6.8182(12) Å, bI, = 3.7113(7) Å, cI=11.0203(17) Å, and face-centred orthorhombic: aII=6.8182(12) Å, bII = 2.7290(3) Å, c II = 11.0203(17) Å. The subcells combine into a coincidence (super)cell with b = 92.79(1) Å, which is 25bI and 34b II. The structure of one of the subcells appears to be related to that of Ca0.82CuO2 and NaCuO2. Sr 0.74CuO2 is non-superconducting, at least above 4 K.

Original languageEnglish
Pages (from-to)1931-1933
Number of pages3
JournalJournal of Materials Chemistry
Volume5
Issue number11
DOIs
Publication statusPublished - 1 Dec 1995
Externally publishedYes

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Sastry, P. V. P. S. S., Robertson, A. D., Lachowski, E. E., Coats, A., & West, A. R. (1995). Synthesis of the new high pressure vernier phase Sr0.74CuO 2. Journal of Materials Chemistry, 5(11), 1931-1933. https://doi.org/10.1039/JM9950501931